UM  > Faculty of Health Sciences
Reductive cleavage of C=C bonds as a new strategy for turn-on dual fluorescence in effective sensing of H2S
Chunfei Wang1; Xiaoxiang Cheng1; Jingyun Tan1; Zhaoyang Ding1; Wenjing Wang2; Daqiang Yuan2; Gang Li1; Hongjie Zhang1; Xuanjun Zhang1
2018-11-28
Source PublicationCHEMICAL SCIENCE
ISSN2041-6520
Volume9Issue:44Pages:8369-8374
Abstract

The discovery of novel reactivities with carbon–carbon double bonds (C=C) is not only useful for chemical synthesis and theoretical studies, but is also important for applications in biology, because C=C bonds are abundant in nature. As we all know, C=C bonds are fundamental structures of alkenes, where the C=C π bond is localized above and below the C–C σ bond wherein π electrons are relatively far away from the nuclei and are loosely bound, so that they can be easily attacked to construct a new bond.1,2 Indeed, addition reactions are one of the common reactions of C=C bonds, such as reactions with HX (X = Cl, Br, I, OH, SH, RS, etc.) as described in Scheme 1a.3 Additionally, C=C bonds can also be cleaved by oxidation as in the typical ozonolysis of alkenes (Scheme 1b).4 However, because of their unique structure, reductive cleavage of alkenes (Csp2–Csp2) has rarely been reported so far.

DOI10.1039/c8sc03430c
Indexed BySCIE
Language英语
WOS Research AreaChemistry
WOS SubjectChemistry, Multidisciplinary
WOS IDWOS:000450436100004
Fulltext Access
Citation statistics
Cited Times [WOS]:20   [WOS Record]     [Related Records in WOS]
Document TypeJournal article
CollectionFaculty of Health Sciences
Corresponding AuthorHongjie Zhang; Xuanjun Zhang
Affiliation1.Faculty of Health Sciences, University of Macau, Macau SAR, China
2.State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
First Author AffilicationFaculty of Health Sciences
Corresponding Author AffilicationFaculty of Health Sciences
Recommended Citation
GB/T 7714
Chunfei Wang,Xiaoxiang Cheng,Jingyun Tan,et al. Reductive cleavage of C=C bonds as a new strategy for turn-on dual fluorescence in effective sensing of H2S[J]. CHEMICAL SCIENCE,2018,9(44):8369-8374.
APA Chunfei Wang,Xiaoxiang Cheng,Jingyun Tan,Zhaoyang Ding,Wenjing Wang,Daqiang Yuan,Gang Li,Hongjie Zhang,&Xuanjun Zhang.(2018).Reductive cleavage of C=C bonds as a new strategy for turn-on dual fluorescence in effective sensing of H2S.CHEMICAL SCIENCE,9(44),8369-8374.
MLA Chunfei Wang,et al."Reductive cleavage of C=C bonds as a new strategy for turn-on dual fluorescence in effective sensing of H2S".CHEMICAL SCIENCE 9.44(2018):8369-8374.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Chunfei Wang]'s Articles
[Xiaoxiang Cheng]'s Articles
[Jingyun Tan]'s Articles
Baidu academic
Similar articles in Baidu academic
[Chunfei Wang]'s Articles
[Xiaoxiang Cheng]'s Articles
[Jingyun Tan]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Chunfei Wang]'s Articles
[Xiaoxiang Cheng]'s Articles
[Jingyun Tan]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.