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Synthesis, crystal structure and nonlinear optical properties of nickel(II) complex with Schiff-base ligand
Xue, ZM1; Zhang, XJ1; Tian, YP1,2,3; Wu, JY1; Jiang, MH2; Fun, HK4
2003
Source PublicationCHINESE JOURNAL OF STRUCTURAL CHEMISTRY
ISSN0254-5861
Volume22Issue:3Pages:265-269
Abstract

The nickel( 11) complex with the new ligand of S-benzyl-beta-N-[10-ethyl-phenothiazine-3-methylene]dithiocarbazate(HL) crystallizes in the triclinic system, space group P (1) over bar with a = 7.516(1), b = 11.322(l), c = 13.366(l) Angstrom, alpha = 84.818(l), beta = 81.688(l), gamma = 76.037(1)degrees, V = 1090.26(3) Angstrom(3), Z = 1, D-c = 1.413 g/cm(3), F(000) = 482, mu(MoKalpha) = 0.774 mm(-1) (lambda = 0.7103 Angstrom), R = 0.0573 and wR = 0, 1375 for 3357 observed reflections with I greater than or equal to 2sigma(I). The HL has lost a proton from its tautomeric thiol form and acts as a single negatively charged bidentate ligand coordinating to the nickel ion via the mercapto sulfur and P-nitrogen atoms. The geometry around Ni( 11) is almost square-planar with two equivalent Ni-N and Ni-S bonds. The nonlinear absorption of HL and NiL2 solutions (in DMF) was measured by open-aperture Z-scan technique at the wavelength of 532 nm.

KeywordCrystal Structure Nlo Complex Nickel
Indexed BySCIE
Language英语
WOS Research AreaChemistry ; Crystallography
WOS SubjectChemistry, Inorganic & Nuclear ; Crystallography
WOS IDWOS:000183147000004
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Cited Times [WOS]:11   [WOS Record]     [Related Records in WOS]
Document TypeJournal article
CollectionFaculty of Health Sciences
Affiliation1.Anhui Univ, Dept Chem, Hefei 230039, Peoples R China
2.Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Peoples R China
3.Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
4.Univ Sains Malaysia, Sch Phys, Xray Crystallog Lab, George Town 11800, Malaysia
Recommended Citation
GB/T 7714
Xue, ZM,Zhang, XJ,Tian, YP,et al. Synthesis, crystal structure and nonlinear optical properties of nickel(II) complex with Schiff-base ligand[J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,2003,22(3):265-269.
APA Xue, ZM,Zhang, XJ,Tian, YP,Wu, JY,Jiang, MH,&Fun, HK.(2003).Synthesis, crystal structure and nonlinear optical properties of nickel(II) complex with Schiff-base ligand.CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,22(3),265-269.
MLA Xue, ZM,et al."Synthesis, crystal structure and nonlinear optical properties of nickel(II) complex with Schiff-base ligand".CHINESE JOURNAL OF STRUCTURAL CHEMISTRY 22.3(2003):265-269.
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