UM
Electrochemical intercalation of Mg2+ in 3D hierarchically porous magnesium cobalt silicate and its application as an advanced cathode material in rechargeable magnesium batteries
Nuli Y.; Zheng Y.; Wang Y.; Yang J.; Wang J.
2011-09-07
Source PublicationJournal of Materials Chemistry
ISSN09599428 13645501
Volume21Issue:33Pages:12437-12443
AbstractWe firstly report the formation of 3D hierarchically porous MgCoSiO and the electrochemical intercalation of the bivalent cation Mg in MgCoSiO with regard to its use as a cathode material in rechargeable magnesium batteries. Reversible Mg intercalation can be demonstrated and the process is enhanced by the use of a novel 3D hierarchically porous architecture, consisting of a network of macropores with several nanometre wall and mesopores at the boundaries of grains or between grains. It is suggested that the interconnected wall structure, dual porosity and high surface area reduces the solid-state diffusion lengths for Mg diffusion, facilitates electrolyte penetration into particles and provides a large number of active sites for charge-transfer reactions. © 2011 The Royal Society of Chemistry.
DOI10.1039/c1jm10485c
URLView the original
Language英語
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Cited Times [WOS]:43   [WOS Record]     [Related Records in WOS]
Document TypeJournal article
CollectionUniversity of Macau
AffiliationShanghai Jiao Tong University
Recommended Citation
GB/T 7714
Nuli Y.,Zheng Y.,Wang Y.,et al. Electrochemical intercalation of Mg2+ in 3D hierarchically porous magnesium cobalt silicate and its application as an advanced cathode material in rechargeable magnesium batteries[J]. Journal of Materials Chemistry,2011,21(33):12437-12443.
APA Nuli Y.,Zheng Y.,Wang Y.,Yang J.,&Wang J..(2011).Electrochemical intercalation of Mg2+ in 3D hierarchically porous magnesium cobalt silicate and its application as an advanced cathode material in rechargeable magnesium batteries.Journal of Materials Chemistry,21(33),12437-12443.
MLA Nuli Y.,et al."Electrochemical intercalation of Mg2+ in 3D hierarchically porous magnesium cobalt silicate and its application as an advanced cathode material in rechargeable magnesium batteries".Journal of Materials Chemistry 21.33(2011):12437-12443.
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