UM
Synthesis of functionalized siloles from Si-tethered diynes
Luo Q.1; Gu L.1; Wang C.1; Liu J.1; Zhang W.1; Xi Z.1
2009-07-01
Source PublicationTetrahedron Letters
ISSN00404039
Volume50Issue:26Pages:3213-3215
AbstractA new synthetic itinerary to silole from Si-tethered diynes is reported. In this protocol, the Si-tethered diyne manifests definitely the reactivity of monoyne to form the lithio silole via zirconacyclopetadiene, 1,4-diiodo-1,3-butadiene, and the corresponding dilithiodiene successively. Lithio siloles thus obtained above could be easily functionalized to give various types of silole derivatives. Complex structure like bridged bis-silole compounds could also be constructed by this process. © 2009 Elsevier Ltd. All rights reserved.
Keyword1,4-Diiodo-1,3-butadiene 1,4-Dilithio-1,3-butadiene Cleavage of Si-C bond Phenyl-bridged bis-silole Si-tethered diynes Silole Zirconacyclopetadiene
DOI10.1016/j.tetlet.2009.01.152
URLView the original
Language英語
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Cited Times [WOS]:12   [WOS Record]     [Related Records in WOS]
Document TypeJournal article
CollectionUniversity of Macau
Affiliation1.Peking University
2.Shanghai Institute of Organic Chemistry Chinese Academy of Sciences
Recommended Citation
GB/T 7714
Luo Q.,Gu L.,Wang C.,et al. Synthesis of functionalized siloles from Si-tethered diynes[J]. Tetrahedron Letters,2009,50(26):3213-3215.
APA Luo Q.,Gu L.,Wang C.,Liu J.,Zhang W.,&Xi Z..(2009).Synthesis of functionalized siloles from Si-tethered diynes.Tetrahedron Letters,50(26),3213-3215.
MLA Luo Q.,et al."Synthesis of functionalized siloles from Si-tethered diynes".Tetrahedron Letters 50.26(2009):3213-3215.
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