| Synthesis of functionalized siloles from Si-tethered diynes | |
| Luo Q.1; Gu L.1; Wang C.1; Liu J.1; Zhang W.1; Xi Z.1 | |
| 2009-07-01 | |
| Source Publication | Tetrahedron Letters
 |
| ISSN | 00404039 |
| Volume | 50Issue:26Pages:3213-3215 |
| Abstract | A new synthetic itinerary to silole from Si-tethered diynes is reported. In this protocol, the Si-tethered diyne manifests definitely the reactivity of monoyne to form the lithio silole via zirconacyclopetadiene, 1,4-diiodo-1,3-butadiene, and the corresponding dilithiodiene successively. Lithio siloles thus obtained above could be easily functionalized to give various types of silole derivatives. Complex structure like bridged bis-silole compounds could also be constructed by this process. © 2009 Elsevier Ltd. All rights reserved. |
| Keyword | 1,4-Diiodo-1,3-butadiene 1,4-Dilithio-1,3-butadiene Cleavage of Si-C bond Phenyl-bridged bis-silole Si-tethered diynes Silole Zirconacyclopetadiene |
| DOI | 10.1016/j.tetlet.2009.01.152 |
| URL | View the original |
| Language | 英語 |
| Fulltext Access | |
| Citation statistics | |
| Document Type | Journal article |
| Collection | University of Macau |
| Affiliation | 1.Peking University 2.Shanghai Institute of Organic Chemistry Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Luo Q.,Gu L.,Wang C.,et al. Synthesis of functionalized siloles from Si-tethered diynes[J]. Tetrahedron Letters,2009,50(26):3213-3215. |
| APA | Luo Q.,Gu L.,Wang C.,Liu J.,Zhang W.,&Xi Z..(2009).Synthesis of functionalized siloles from Si-tethered diynes.Tetrahedron Letters,50(26),3213-3215. |
| MLA | Luo Q.,et al."Synthesis of functionalized siloles from Si-tethered diynes".Tetrahedron Letters 50.26(2009):3213-3215. |
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