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Opening the silole ring: Efficient and specific cleavage of the endo-C(sp2)-Si bond with AcOH/ROH system
Luo Q.4; Wang C.2; Li Y.4; Ouyang K.4; Gu L.4; Uchiyama M.2; Xi Z.4
2011-11-01
Source PublicationChemical Science
ISSN20416520 20416539
Volume2Issue:11Pages:2271-2274
AbstractAn efficient and specific cleavage of the endo-C(sp)-Si bond of silole rings was developed. The stable silole ring was effectively opened in an unexpected regioselectivity by using an AcOH/ROH system, in which the AcOH behaved as a catalyst and the ROH as a nucleophile. Depending on the nature of the substituents at the 2- and 5-positions of the silole ring, the cooperative effect of the AcOH/ROH system exclusively cleaved one of the two endo-C-Si bonds to afford silylbutadiene derivatives. © The Royal Society of Chemistry 2011.
DOI10.1039/c1sc00356a
URLView the original
Language英語
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Cited Times [WOS]:14   [WOS Record]     [Related Records in WOS]
Document TypeJournal article
CollectionUniversity of Macau
Affiliation1.Riken
2.University of Tokyo
3.Chinese Academy of Sciences
4.Peking University
Recommended Citation
GB/T 7714
Luo Q.,Wang C.,Li Y.,et al. Opening the silole ring: Efficient and specific cleavage of the endo-C(sp2)-Si bond with AcOH/ROH system[J]. Chemical Science,2011,2(11):2271-2274.
APA Luo Q..,Wang C..,Li Y..,Ouyang K..,Gu L..,...&Xi Z..(2011).Opening the silole ring: Efficient and specific cleavage of the endo-C(sp2)-Si bond with AcOH/ROH system.Chemical Science,2(11),2271-2274.
MLA Luo Q.,et al."Opening the silole ring: Efficient and specific cleavage of the endo-C(sp2)-Si bond with AcOH/ROH system".Chemical Science 2.11(2011):2271-2274.
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