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BrOnsted Base-Mediated Aziridination of 2-Alkyl-Substituted-1,3-Dicarbonyl Compounds and 2-Acyl-Substituted-1,4-Dicarbonyl Compounds by Iminoiodanes
Tejo, Ciputra1; Tirtorahardjo, Davin1; Day, David Philip2; Ma, Dik-Lung3; Leung, Chung-Hang4; Chan, Philip Wai Hong2,5
2017
Source PublicationAUSTRALIAN JOURNAL OF CHEMISTRY
ISSN0004-9425
Volume70Issue:4Pages:430-435
Abstract

The synthesis of ,-diacylaziridines and ,,-triacylaziridines from reaction of 2-alkyl-substituted-1,3-dicarbonyl compounds and 2-acyl-substituted-1,4-dicarbonyl compounds with arylsulfonyliminoiodinanes (ArSO2N=IPh) under BrOnsted base-mediated atmospheric conditions is described. The reaction mechanism is thought to involve the formal oxidation of the substrate followed by aziridination of the ensuing ,-unsaturated intermediate by the hypervalent iodine(iii) reagent.

DOI10.1071/CH16580
URLView the original
Indexed BySCI ; IC ; CCR
Language英语
WOS Research AreaChemistry
WOS SubjectChemistry, Multidisciplinary
WOS IDWOS:000398533900011
PublisherCSIRO PUBLISHING
The Source to ArticleWOS
Fulltext Access
Citation statistics
Cited Times [WOS]:3   [WOS Record]     [Related Records in WOS]
Document TypeJournal article
CollectionInstitute of Chinese Medical Sciences
Corresponding AuthorChan, Philip Wai Hong
Affiliation1.Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore
2.Department of Chemistry, University of Warwick, Coventry, CV4 7AL, UK
3.Department of Chemistry, Hong Kong Baptist University, Kowloon Tong, Hong Kong, China
4.State Key Laboratory of Quality Research in Chinese Medicine, Institute of Chinese Medical Sciences, University of Macau, Macao, China
5.School of Chemistry, Monash University, Clayton, Vic. 3800, Australia
Recommended Citation
GB/T 7714
Tejo, Ciputra,Tirtorahardjo, Davin,Day, David Philip,et al. BrOnsted Base-Mediated Aziridination of 2-Alkyl-Substituted-1,3-Dicarbonyl Compounds and 2-Acyl-Substituted-1,4-Dicarbonyl Compounds by Iminoiodanes[J]. AUSTRALIAN JOURNAL OF CHEMISTRY,2017,70(4):430-435.
APA Tejo, Ciputra,Tirtorahardjo, Davin,Day, David Philip,Ma, Dik-Lung,Leung, Chung-Hang,&Chan, Philip Wai Hong.(2017).BrOnsted Base-Mediated Aziridination of 2-Alkyl-Substituted-1,3-Dicarbonyl Compounds and 2-Acyl-Substituted-1,4-Dicarbonyl Compounds by Iminoiodanes.AUSTRALIAN JOURNAL OF CHEMISTRY,70(4),430-435.
MLA Tejo, Ciputra,et al."BrOnsted Base-Mediated Aziridination of 2-Alkyl-Substituted-1,3-Dicarbonyl Compounds and 2-Acyl-Substituted-1,4-Dicarbonyl Compounds by Iminoiodanes".AUSTRALIAN JOURNAL OF CHEMISTRY 70.4(2017):430-435.
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