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Structural, dielectric and Mossbauer studies of PbFe0.5Sb0.5O3 ceramics with differing degree of compositional ordering
Raevski I.P.3; Pushkarev A.V.1; Raevskaya S.I.3; Olekhnovich N.M.1; Radyush Y.V.1; Kubrin S.P.3; Chen H.4; Chou C.-C.2; Sarychev D.A.3; Titov V.V.3; Malitskaya M.A.3
2016-09-01
Source PublicationFerroelectrics
ISSN15635112 00150193
Volume501Issue:1Pages:154-164
Abstract

Ceramic samples of a new perovskite multiferroic PbFeSbO (PFS) with a differing degree S of long-range compositional ordering of the Fe and Sb cations were fabricated by a variation of the high-pressure-synthesis conditions. The S values estimated from the XRD data varied from 0.93 down to 0.17. The unit cell parameter was found to decrease with increasing S. In line with these results the fraction of the singlet component in the Mössbauer spectra was found to decrease with decreasing S. However, the temperatures and diffusion of dielectric permittivity maxima as well as the temperature of magnetic phase transition determined from Mössbauer data do not change substantially with S. These results imply that PFS remains highly ordered at the nanoscale.

KeywordMossbauer Effect Multiferroic Ordering Pbfe0.5sb0.5o3 Phase Transition
DOI10.1080/00150193.2016.1204196
URLView the original
Indexed BySCI
Language英语
WOS Research AreaMaterials Science ; Physics
WOS SubjectMaterials Science, Multidisciplinary ; Physics, Condensed Matter
WOS IDWOS:000386599200022
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被引频次[WOS]:3   [WOS记录]     [WOS相关记录]
Document TypeJournal article
专题INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Affiliation1.Scientific Practical Materials Research Centre of NAS of Belarus
2.National Taiwan University of Science and Technology
3.Southern Federal University
4.Universidade de Macau
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Raevski I.P.,Pushkarev A.V.,Raevskaya S.I.,et al. Structural, dielectric and Mossbauer studies of PbFe0.5Sb0.5O3 ceramics with differing degree of compositional ordering[J]. Ferroelectrics,2016,501(1):154-164.
APA Raevski I.P..,Pushkarev A.V..,Raevskaya S.I..,Olekhnovich N.M..,Radyush Y.V..,...&Malitskaya M.A..(2016).Structural, dielectric and Mossbauer studies of PbFe0.5Sb0.5O3 ceramics with differing degree of compositional ordering.Ferroelectrics,501(1),154-164.
MLA Raevski I.P.,et al."Structural, dielectric and Mossbauer studies of PbFe0.5Sb0.5O3 ceramics with differing degree of compositional ordering".Ferroelectrics 501.1(2016):154-164.
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