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Defining the composition and electronic structure of large-scale and single-crystalline like Cs 2 AgBiBr 6 films fabricated by capillary-assisted dip-coating method
Xiu J.1; Shao Y.1; Chen L.1; Feng Y.1; Dai J.1; Zhang X.1; Lin Y.1; Zhu Y.1; Wu Z.1; Zheng Y.1; Pan H.2; Liu C.1; Shi X.1; Cheng X.1; He Z.1
2019-06-01
Source PublicationMaterials Today Energy
ISSN24686069
Volume12Pages:186-197
Abstract

Owning the merits of both lead-free and air-stable, the double-perovskite Cs AgBiBr has attracted increasing attention, but suffers low visible-light absorption coefficient due to its large indirect bandgap. Moreover, the electronic structure of its synthesized films has not been explored clearly yet. In this work, we developed a general and promising method to fabricate continuous, uniform and highly orientated Cs AgBiBr films in large scale on various substrates through capillary-assisted dip-coating method. Strikingly, those optimized films are single crystalline verified by φ-scan XRD. Its electronic structure was carefully studied independently by multi-photo-physical characterizations. Its bandgap can be tuned from 2.65 to 2.25 eV by changing the substrate temperature in growth from 40 to 160 °C. Essentially, their work-function (WF) was determined at −5.01 eV and WF-VBM is around 2 eV. This novel band structure with typical n-type characteristic, was further confirmed by DFT calculations, which reveals that the Cs interstitials and Br vacancies derived deep defect levels were fixed around its Fermi level, closer to the conduction band. This conclusion is different from its widely accepted p-type feature, but definitely deepens our understanding of this material and inspires us to find more valuable strategies of modulating its band structure and optoelectronic properties.

KeywordSingle-crystalline Perovskite Films
DOI10.1016/j.mtener.2019.01.010
URLView the original
Language英语
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Document TypeJournal article
CollectionInstitute of Applied Physics and Materials Engineering
Affiliation1.Southern University of Science and Technology
2.Universidade de Macau
Recommended Citation
GB/T 7714
Xiu J.,Shao Y.,Chen L.,et al. Defining the composition and electronic structure of large-scale and single-crystalline like Cs 2 AgBiBr 6 films fabricated by capillary-assisted dip-coating method[J]. Materials Today Energy,2019,12:186-197.
APA Xiu J..,Shao Y..,Chen L..,Feng Y..,Dai J..,...&He Z..(2019).Defining the composition and electronic structure of large-scale and single-crystalline like Cs 2 AgBiBr 6 films fabricated by capillary-assisted dip-coating method.Materials Today Energy,12,186-197.
MLA Xiu J.,et al."Defining the composition and electronic structure of large-scale and single-crystalline like Cs 2 AgBiBr 6 films fabricated by capillary-assisted dip-coating method".Materials Today Energy 12(2019):186-197.
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