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Two novel two-photon polymerization initiators with extensive application prospects
Tian, YP1,2,3; Zhang, ML1; Yu, XQ2; Xu, GB2; Ren, Y2; Yang, JX2; Wu, JY1; Zhang, XJ1; Tao, XT2; Zhang, SY1; Jiang, MH2
2004
Source PublicationCHEMICAL PHYSICS LETTERS
ISSN0009-2614
Volume388Issue:4-6Pages:325-329
Abstract

Two novel two-photon polymerization initiators, 10-etliyl-3-E-(4-(N,N'-di-n-butylamino)styryl)phenothiazine 5 and 10-ethyl-3,7-E,E-bis(4-(N,N'-di-n-butyl amino)styryl)phenothiazine 6, have been efficiently synthesized with room temperature solid phase Wittig reaction. Two initiators were found to exhibit good single-photon fluorescence emission and their quantum yields, lifetimes and solvent effects have been studied in detail. Two-photonfluorescence spectra were investigated under 800 nm fs laser pulse and two-photon absorption (TPA) cross-sections of the initiators have been evaluated by theoretical calculation. Two-photon initiating polymerization microfabrication experiments have been carried out and artificial defects were made and polymerization mechanism was also discussed. (C) 2004 Elsevier B.V. All rights reserved.

DOIhttp://dx.doi.org/10.1016/j.cplett.2004.02.099
Indexed BySCIE
Language英语
WOS Research AreaChemistry ; Physics
WOS SubjectChemistry, Physical ; Physics, Atomic, Molecular & Chemical
WOS IDWOS:000220935600018
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Cited Times [WOS]:26   [WOS Record]     [Related Records in WOS]
Document TypeJournal article
CollectionFaculty of Health Sciences
Affiliation1.Department of Chemistry, Anhui University, Longhe route, Hefei 230039, PR China
2.State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, PR China
3.State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, PR China
Recommended Citation
GB/T 7714
Tian, YP,Zhang, ML,Yu, XQ,et al. Two novel two-photon polymerization initiators with extensive application prospects[J]. CHEMICAL PHYSICS LETTERS,2004,388(4-6):325-329.
APA Tian, YP.,Zhang, ML.,Yu, XQ.,Xu, GB.,Ren, Y.,...&Jiang, MH.(2004).Two novel two-photon polymerization initiators with extensive application prospects.CHEMICAL PHYSICS LETTERS,388(4-6),325-329.
MLA Tian, YP,et al."Two novel two-photon polymerization initiators with extensive application prospects".CHEMICAL PHYSICS LETTERS 388.4-6(2004):325-329.
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