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Synthesis, crystal structure and two-photon property studies on a series of complexes derived from a novel Schiff base ligand
Ming-Liang Zhang1; Yu-Peng Tian1; Xuan-Jun Zhang1; Jie-Ying Wu1; Sheng-Yi Zhang1; Dong Wang2; Min-Hua Jiang2; Suchada Chantrapromm3,4; Hoong-Kun Fun3
2004
Source PublicationTRANSITION METAL CHEMISTRY
ISSN0340-4285
Volume29Issue:6Pages:596-602
Abstract

A new Schiff base ligand derived from S-benzyldithiocarbazate and 4-[N-hydroxy ethyl-N-(methyl)amino]benzaldehyde (HL, where H is a dissociable proton) and its Ni-II, Cu-II, Zn-II and Pd-II complexes were prepared and fully characterized. The structures of HL and Ni(L)(2) were determined by X-ray diffraction analysis, which revealed that the geometry of the Ni-II ion is square-planar with two equivalent Ni-N and Ni-S bonds, and that the two neighboring molecules in two layers have weak contact. The electronic spectra and solution fluorescence of the ligand and the complexes were studied, and the quantum yields of single-photon fluorescence for the compounds were determined. The compounds possess two-photon absorption (t.p.a.) character and the t.p.a. coefficient beta and t.p.a. cross-section sigma were determined by the Z-scan technique. Especially, the Zn(L)(2) complex and the HL ligand exhibit intensive two-photon fluorescence (t.p.f.) at 800 nm laser pulses in the femtosecond regime.

DOIhttp://dx.doi.org/10.1007/s11243-004-1208-2
Indexed BySCI
Language英语
WOS Research AreaChemistry
WOS SubjectChemistry, Inorganic & Nuclear
WOS IDWOS:000225300200004
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Cited Times [WOS]:15   [WOS Record]     [Related Records in WOS]
Document TypeJournal article
CollectionFaculty of Health Sciences
Affiliation1.Department of ChemistryAnhui University, HefeiAnhuiP.R. China
2.State Key Laboratory of Crystal MaterialsShandong UniversityJinanP.R. China
3.Crystallography Unit, School of PhysicsUniversiti Sain MalaysiaPenangMalaysia
4.Crystallography Unit, School of PhysicsUniversiti Sain MalaysiaPenangMalaysia
Recommended Citation
GB/T 7714
Ming-Liang Zhang,Yu-Peng Tian,Xuan-Jun Zhang,et al. Synthesis, crystal structure and two-photon property studies on a series of complexes derived from a novel Schiff base ligand[J]. TRANSITION METAL CHEMISTRY,2004,29(6):596-602.
APA Ming-Liang Zhang.,Yu-Peng Tian.,Xuan-Jun Zhang.,Jie-Ying Wu.,Sheng-Yi Zhang.,...&Hoong-Kun Fun.(2004).Synthesis, crystal structure and two-photon property studies on a series of complexes derived from a novel Schiff base ligand.TRANSITION METAL CHEMISTRY,29(6),596-602.
MLA Ming-Liang Zhang,et al."Synthesis, crystal structure and two-photon property studies on a series of complexes derived from a novel Schiff base ligand".TRANSITION METAL CHEMISTRY 29.6(2004):596-602.
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