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Synthesis, crystal structure and NLO properties of a novel ruthenium(II) complex with unusual coordination mode
Yu-Peng Tian1; Ming-Liang Zhang1; Zhang-Jun Hu1; Han-Mei Hu1; Jie-Ying Wu1; Xuan-Jun Zhang1; Sheng-Yi Zhang1; Xu-Tang Tao2; Min-Hua Jiang2; He-Ping Chen3; Suchada Chantrapromma4; Hoong-Kun Fun4
2005
Source PublicationTRANSITION METAL CHEMISTRY
ISSN0340-4285
Volume30Issue:7Pages:778-785
Abstract

A new Schiff base 4-[N-hydroxyethyl-N-(methyl)amino]benzaldehyde S-methyl dithiocarbazate (HL, where H is a dissociable proton) and the ruthenium complex [Ru(bpy)2L]PF6 (bpy = 2,2¢-bipyridine) have been synthesized. The structural determinations of the ligand and its ruthenium complex, by X-ray crystallography, show that the ligand is coordinated as a monoanionic bidentate N, S-donor, forming a four-member chelate ring with a bite angle of 65.91. The complex shows intense MLCT transitions in the visible region. Fluorescent and electrochemical properties have been also studied. The complex in DMF solution exhibited a strong twophoton absorption (t.p.a.) at 532 nm nanosecond laser pulses. The t.p.a. coefficient b, t.p.a. cross-section r and the third-order optical nonlinearity v(3) of the complex and the ligand have been determined by the Z-scan technique.

DOIhttp://dx.doi.org/10.1007/s11243-005-4825-5
Indexed BySCI
Language英语
WOS Research AreaChemistry
WOS SubjectChemistry, Inorganic & Nuclear
WOS IDWOS:000232053900002
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Cited Times [WOS]:19   [WOS Record]     [Related Records in WOS]
Document TypeJournal article
CollectionFaculty of Health Sciences
Affiliation1.Department of Chemistry, Anhui University, Hefei 230039, P.R. China
2.State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, P.R. China
3.Department of Physics, Anhui University, Hefei 230039, P.R. China
4.Crystallography Unit, School of Physics, Universiti Sain Malaysia, USM 11800, Penang, Malaysia
Recommended Citation
GB/T 7714
Yu-Peng Tian,Ming-Liang Zhang,Zhang-Jun Hu,et al. Synthesis, crystal structure and NLO properties of a novel ruthenium(II) complex with unusual coordination mode[J]. TRANSITION METAL CHEMISTRY,2005,30(7):778-785.
APA Yu-Peng Tian.,Ming-Liang Zhang.,Zhang-Jun Hu.,Han-Mei Hu.,Jie-Ying Wu.,...&Hoong-Kun Fun.(2005).Synthesis, crystal structure and NLO properties of a novel ruthenium(II) complex with unusual coordination mode.TRANSITION METAL CHEMISTRY,30(7),778-785.
MLA Yu-Peng Tian,et al."Synthesis, crystal structure and NLO properties of a novel ruthenium(II) complex with unusual coordination mode".TRANSITION METAL CHEMISTRY 30.7(2005):778-785.
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