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Influence of the central metal on the crystal structures and electronic structures of biferrocene trinuclear complexes
Liu, ZD1; Zhang, XJ1; Wu, JY1; Hao, FY1; Zhou, HP1; Tian, YP1,2,3
2011
Source PublicationPOLYHEDRON
ISSN0277-5387
Volume30Issue:2Pages:279-283
Abstract

Five metal-bridged biferrocene complexes of the Schiff-base ligand (HL=S-benzyl-N-(ferrocenyl-1-methyl-methylidene)dithiocarbazate) have been studied by single crystal X-ray diffraction and (57)Fe Mossbauer spectroscopy. The crystal structures of the complexes show that the central metal ions are tetra-coordinated by two ligands in two modes: the central d(8) transition metal ions (Ni(2+), Pd(2+), and Pt(2+)) are nearly square-planar coordinated and the d(10) transition metal ions (Zn(2+) and Cd(2+)) are tetrahedrally coordinated. Interestingly, the isomer shifts in (57)Fe Mossbauer spectroscopy are also of two kinds: d(8) transition metal ions (0.097-0.247 mm/s) and d(10) transition metal ions (0.416-0.435 mm/s). (C) 2010 Elsevier Ltd. All rights reserved.

KeywordBiferrocene Trinuclear Complexes (57)Fe Mossbauer Spectroscopy Crystal Structure
DOIhttp://dx.doi.org/10.1016/j.poly.2010.10.022
Indexed BySCI
Language英语
WOS Research AreaChemistry ; Crystallography
WOS SubjectChemistry, Inorganic & Nuclear ; Crystallography
WOS IDWOS:000287343100011
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Cited Times [WOS]:2   [WOS Record]     [Related Records in WOS]
Document TypeJournal article
CollectionFaculty of Health Sciences
Affiliation1.Anhui Univ, Dept Chem, Key Lab Funct Inorgan Mat Anhui Prov, Hefei 230039, Peoples R China
2.Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Peoples R China
3.Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
Recommended Citation
GB/T 7714
Liu, ZD,Zhang, XJ,Wu, JY,et al. Influence of the central metal on the crystal structures and electronic structures of biferrocene trinuclear complexes[J]. POLYHEDRON,2011,30(2):279-283.
APA Liu, ZD,Zhang, XJ,Wu, JY,Hao, FY,Zhou, HP,&Tian, YP.(2011).Influence of the central metal on the crystal structures and electronic structures of biferrocene trinuclear complexes.POLYHEDRON,30(2),279-283.
MLA Liu, ZD,et al."Influence of the central metal on the crystal structures and electronic structures of biferrocene trinuclear complexes".POLYHEDRON 30.2(2011):279-283.
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