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Formation of a novel 1D supramolecule [HgCl2(ptz)](2)center dot HgCl2 (ptz = phenothiazine): A new precursor to submicrometer Hg2Cl2 rods
Xuanjun Zhang1; Yi Xie1; Wentao Yu2; Qingrui Zhao1; Minhua Jiang2; Yupeng Tian3
2003
Source PublicationInorganic Chemistry
ISSN0020-1669
Volume42Issue:12Pages:3734–3737
Abstract

A novel supramolecule [HgCl2(ptz)]2‚HgCl2 (ptz ) phenothiazine) with uncoordinated inorganic salt HgCl2 presented in a 1D chain was first prepared and then successfully applied as a new precursor in the preparation of submicrometer Hg2Cl2 rods. Single crystal X-ray analysis showed that the 1D chain structure is stabilized by hydrogen bonds between adjacent chains and the coordination mode of the ligand phenothiazine is unusual with large steric inhibition other than the chain directions. The results revealed that the particular chain structure plays a significant role in the formation of the Hg2Cl2 rods.

DOIhttp://dx.doi.org/10.1021/ic034055o
Indexed BySCI
Language英语
WOS Research AreaChemistry
WOS SubjectChemistry, Inorganic & Nuclear
WOS IDWOS:000183410900008
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Citation statistics
Document TypeJournal article
CollectionFaculty of Health Sciences
Affiliation1.University of Science and Technology of China.
2.Shandong University.
3.Anhui University.
Recommended Citation
GB/T 7714
Xuanjun Zhang,Yi Xie,Wentao Yu,et al. Formation of a novel 1D supramolecule [HgCl2(ptz)](2)center dot HgCl2 (ptz = phenothiazine): A new precursor to submicrometer Hg2Cl2 rods[J]. Inorganic Chemistry,2003,42(12):3734–3737.
APA Xuanjun Zhang,Yi Xie,Wentao Yu,Qingrui Zhao,Minhua Jiang,&Yupeng Tian.(2003).Formation of a novel 1D supramolecule [HgCl2(ptz)](2)center dot HgCl2 (ptz = phenothiazine): A new precursor to submicrometer Hg2Cl2 rods.Inorganic Chemistry,42(12),3734–3737.
MLA Xuanjun Zhang,et al."Formation of a novel 1D supramolecule [HgCl2(ptz)](2)center dot HgCl2 (ptz = phenothiazine): A new precursor to submicrometer Hg2Cl2 rods".Inorganic Chemistry 42.12(2003):3734–3737.
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